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Effects of sulfur on variations in the chemical speciation of heavy metals from fly ash glass

《环境科学与工程前沿（英文）》 2023年 第17卷 第10期 doi: 10.1007/s11783-023-1728-7

摘要：

● A higher sulfur content reduced the curing rate of Cr in glass.

关键词： Dechlorinated fly ash     SO3     Heavy metal     Chemical speciation     Glass solidification    

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Trends of chemical speciation profiles of anthropogenic volatile organic compounds emissions in China

Wei WEI, Shuxiao WANG, Jiming HAO, Shuiyuan CHENG

《环境科学与工程前沿（英文）》 2014年 第8卷 第1期   页码 27-41 doi: 10.1007/s11783-012-0461-4

摘要： This study estimates the detailed chemical profiles of China’s anthropogenic volatile organic compounds (VOCs) emissions for the period of 2005–2020. The chemical profiles of VOCs for seven activity sectors are calculated, based on which the Photochemical Ozone Creation Potential (POCP) of VOCs for these sectors is evaluated. At the national level, the VOCs species emitted in 2005 include alkanes, alkenes and alkynes, aromatic compounds, alcohols, ketones, aldehydes, esters, ethers and halocarbons, accounting for 26.4 wt.%, 29.2 wt.%, 21.3 wt.%, 4.7 wt.%, 5.4 wt.%, 1.7 wt.%, 2.1 wt.%, 0.7 wt.% and 2.2 wt.% of total emissions, respectively. And during 2005-2020, their mass proportions would respectively grow or decrease by -6.9%, -32.7%, 7.3%, 65.3%, 34.7%, -48.6%, 108.5%, 100.5%, and 55.4%. This change would bring about a 13% reduction of POCP for national VOCs emissions in the future. Thus, although the national VOCs emissions are expected to increase by 33% over the whole period, its ozone formation potential is estimated to rise only by 14%. Large discrepancies are found in VOCs speciation emissions among provinces. Compared to western provinces, the eastern provinces with a more developed economy would emit unsaturated hydrocarbons and benzene with lower mix ratios, and aromatic compounds except benzene, oxidized hydrocarbons and halocarbons with higher mix ratios. Such differences lead to lower POCP of VOCs emitted in eastern provinces, and higher POCP of VOCs emitted in western provinces. However, due to the large VOCs emissions from Chinese eastern region, the ozone formation potential of VOCs emission in eastern provinces would be much higher than those in western provinces by about 156%–235%.

关键词： volatile organic compounds (VOCs)     chemical speciation     ozone formation     Photochemical Ozone Creation Potential (POCP)     China    

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Chemical speciation and anthropogenic sources of ambient volatile organic compounds (VOCs) during summer

LU Sihua, LIU Ying, SHAO Min, HUANG Shan

《环境科学与工程前沿（英文）》 2007年 第1卷 第2期   页码 147-152 doi: 10.1007/s11783-007-0026-0

摘要： Volatile organic compounds (VOCs) were measured at six sites in Beijing in August, 2004. Up to 148 VOC species, including C to C alkanes, C to C alkenes, C to C aromatics, and halogenated hydrocarbons, were quantified. Although the concentrations differed at the sites, the chemical compositions were similar, except for the Tongzhou site where aromatics were significantly high in the air. Based on the source profiles measured from previous studies, the source apportionment of ambient VOCs was preformed by deploying the chemical mass balance (CMB) model. The results show that urban VOCs are predominant from mobile source emissions, which contribute more than 50% of the VOCs (in mass concentrations) to ambient air at most sites. Other important sources are gasoline evaporation, painting, and solvents. The exception is at the Tongzhou site where vehicle exhaust, painting, and solvents have about equal contribution, around 35% of the ambient VOC concentration. As the receptor model is not valid for deriving the sources of reactive species, such as isoprene and 1,3-butadiene, other methodologies need to be further explored.

关键词： Beijing     exception     gasoline evaporation     August     exhaust    

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Sequence of the main geochemical controls on the Cu and Zn fractions in the Yangtze River estuarine sediments

Shou ZHAO,Dongxin WANG,Chenghong FENG,Ying WANG,Zhenyao SHEN

《环境科学与工程前沿（英文）》 2016年 第10卷 第1期   页码 19-27 doi: 10.1007/s11783-014-0723-4

摘要： Metal speciation can provide sufficient information for environmental and geochemical researches. In this study, based on the speciation determination of Cu and Zn in the Yangtze Estuary sediments, roles of eight geochemical controls (i.e., total organic carbon (TOC), clay, Fe/Mn in five chemical fractions and salinity) are fully investigated and sequenced with correlation analysis (CA) and principal components analysis (PCA). Results show that TOC, clay and Fe/Mn oxides are key geochemical factors affecting the chemical speciation distributions of Cu and Zn in sediments, while the role of salinity appears to be more indirect effect. The influencing sequence generally follows the order: TOC>clay>Mn oxides>Fe oxides>salinity. Among the different fractions of Fe/Mn oxides, residual and total Fe content, and exchangeable and carbonate Mn exert the greatest influences, while exchangeable Fe and residual Mn show the poorest influences.

关键词： chemical speciation     geochemical factors     estuaries     sediments     correlation     salinity    

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Effect of lime on speciation of heavy metals during composting of water hyacinth

Jiwan SINGH,Ajay S. KALAMDHAD

《环境科学与工程前沿（英文）》 2016年 第10卷 第1期   页码 93-102 doi: 10.1007/s11783-014-0704-7

摘要： Composting is attractive and inexpensive method for treatment and biomass disposal of water hyacinth. However, the major disadvantage of water hyacinth composting is the high content of heavy metals in the final compost. Addition of lime sludge significantly reduced most bioavailable fractions (exchangeable and carbonate) of heavy metals. Studies were carried on composting of water hyacinth ( ) with cattle manure and sawdust (6:3:1 ratio) and effects of addition of lime (1%, 2% and 3%) on heavy metal speciation were evaluated during 30 days of composting period. The Tessier sequential extraction method was employed to investigate the changes in speciation of heavy metals such as Zinc (Zn), Copper (Cu), Manganese (Mn), Iron (Fe), Lead (Pb), Nickel (Ni), Cadmium (Cd) and Chromium (Cr) during water hyacinth composting. Effects of physicochemical parameters such as temperature, pH and organic matter on speciation of heavy metals were also studied during the process. Results showed that, the total metal content was increased during the composting process. The higher reduction in bioavailability factor (BF) of Cu, Fe, Ni, Cd and Cr was observed in lime 2 treatment about 62.1%, 64.4%, 71.9%, 62.1% and 58.9% respectively; however higher reduction in BF of Zn and Pb was observed in lime 1 treatment during the composting process. Reducible and oxidizable fractions of Ni, Pb and Cd were not observed during the process. Addition of lime was very effective for reduction of bioavailability of heavy metals during composting of water hyacinth with cattle manure and sawdust.

关键词： composting     lime     heavy metals     bioavailability factor     speciation    

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Comparison of masking agents for antimony speciation analysis using hydride generation atomic fluorescence

Jianhong XI,Mengchang HE,Kunpeng WANG,Guizhi ZHANG

《环境科学与工程前沿（英文）》 2015年 第9卷 第6期   页码 970-978 doi: 10.1007/s11783-014-0716-3

摘要： A sensitive atomic spectrometric method for the redox speciation analysis of Sb in water is described. The proposed method is based on the selective generation of stibine from Sb(III) in a continuous flow system using non-dispersive atomic fluorescence spectrometry for detection. The effects of the HCl concentration on the fluorescence intensities of Sb(III) and Sb(V) were investigated. The results indicated that atomic fluorescence emission due to Sb(V) can constructively interfere with the determination of Sb(III). For the determination of Sb(III), four compounds were tested as masking agents to inhibit the generation of stibine from Sb(V). The effects of the concentrations of the masking agents and of HCl on the fluorescence signals from Sb(III) and Sb(V) were studied. The results indicated that citric acid and NaF can successfully suppress hydride generation from Sb(V). To evaluate the developed methodology and the influence of the matrix, the recovery of Sb(III) from natural water that was spiked with different Sb(III) and Sb(V) concentrations was tested.

关键词： Sb(III)     Sb(V)     determination     masking agents     hydride generation (HG-AFS)    

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The speciation, leachability and bioaccessibility of Cu and Zn in animal manure-derived biochar: effect

Qi Lin, Xin Xu, Lihua, Wang, Qian Chen, Jing Fang, Xiaodong Shen, Liping Lou, Guangming Tian

《环境科学与工程前沿（英文）》 2017年 第11卷 第3期 doi: 10.1007/s11783-017-0924-8

摘要： Biochars derived from animal manures may accumulate potentially toxic metals and cause a potential risk to ecosystem. The synchrotron-based X-ray spectroscopy, sequential fractionation schemes, bioaccessibility extraction and leaching procedure were performed on poultry and swine manure-derived biochars (denoted PB and SB, respectively) to evaluate the variance of speciation and activity of Cu and Zn as affected by the feedstock and pyrolysis temperature. The results showed that Cu speciation was dependent on the feedstock with Cu-citrate-like in swine manure and species resembling Cu-glutathione and CuO in poultry manure. Pyrolyzed products, however, had similar Cu speciation mainly with species resembling Cu-citrate, CuO and CuS/Cu S. Organic bound Zn and Zn (PO ) -like species were dominant in both feedstock and biochars. Both Cu and Zn leaching with synthetic precipitation leaching procedure (SPLP) and toxicity characteristic leaching procedure (TCLP) decreased greatly with the rise of pyrolysis temperature, which were consistent with the sequential extraction results that pyrolysis converted Cu and Zn into less labile phases such as organic/sulfide and residual fractions. The potential bioaccessibility of Zn decreased for both the PB and SB, closely depending on the content of non-residual Zn. The bioaccessibility of Cu, however, increased for the SB prepared at 300°C–700°C, probably due to the increased proportion of CuO. Concerning the results of sequential fractionation schemes, bioaccessibility extraction and leaching procedure, pyrolysis at 500°C was suggested as means of reducing Cu/Zn lability and poultry manure was more suitable for pyrolysis treatment.

关键词： Animal manure     Biochar     Metals     Molecular species     Pyrolysis    

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Speciation evolutions of target metals (Cd, Pb) influenced by chlorine and sulfur during sewage sludge

Jingde LUAN,Rundong LI,Zhihui ZHANG,Yanlong LI,Yun ZHAO

《环境科学与工程前沿（英文）》 2014年 第8卷 第6期   页码 871-876 doi: 10.1007/s11783-013-0621-1

摘要： In sludge incineration, the thermal behavior of heavy metal is a growing concern. In this work, the combined analysis of metal partitioning behavior between vapor phase and condensed phase, speciation redistribution in condensed phase and the difference of metal species in binding energy was carried out to investigate the possible volatilization-condensation mechanism of heavy metals in high-temperature sludge incineration. It was found that there were two steps in metal volatilization. The initial volatilization of heavy metal originated from their exchangeable (EXC), carbonate bound (CAR) and iron–manganese bound (FM) fractions, which is primarily composed of simple substance, chlorides, oxides and sulfides. With the increase of chlorine and sulfur in sludge, the inner speciation redistribution of heavy metals occurred in condensed phase, which was an important factor affecting the potential volatility of heavy metals. A partial of metal species with complexed (COM) and residual (RES) fractions gradually decomposed into simple substance or ions, oxides and carbonates, which significantly strengthened the second volatility. In presence of chlorine, about 46% of Cd with the RES fraction disappeared when the volatility rate of Cd increased by 44.89%. Moreover, about 9% of Pb with COM fraction disappeared when there was an increase of nearly 10% in the volatilization rate. Thus, the second volatilization was mainly controlled by the decomposition of metal species with COM and RES fractions. By virtue of XRD analysis and the binding energy calculation, it was found that metal complex and silicates were inclined to decompose under high temperature due to poor thermo stability as compared with sulfates.

关键词： sludge incineration     heavy metals     inner speciation redistribution     binding energy    

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Recycling from Waste Light-Emitting Diode Under Hydrothermal Condition: Plastic Package Degradation, Speciation

Yongliang Zhang,Lu Zhan,Zhenming Xu,

《工程（英文）》 doi: 10.1016/j.eng.2023.04.008

摘要： Light emitting diodes (LEDs) have accounted for most of the lighting market as the technology matures and costs continue to reduce. As a new type of e-waste, LED is a double-edged sword, as it contains not only precious and rare metals but also organic packaging materials. In previous studies, LED recycling focused on recovering precious and strategic metals while ignoring harmful substances such as organic packaging materials. Unlike crushing and other traditional methods, hydrothermal treatment can provide an environment-friendly process for decomposing packaging materials. This work developed a closed reaction vessel, where the degradation rate of plastic polyphthalamide (PPA) was close to 100%, with nano-TiO2 encapsulated in plastic PPA being efficiently recovered, while metals contained in LED were also recycled efficiently. Besides, the role of water in plastic PPA degradation that has been overlooked in current studies was explored and speculated in detail in this work. Environmental impact assessment revealed that the proposed recycling route for waste LED could significantly reduce the overall environmental impact compared to the currently published processes. Especially the developed method could reduce more than half the impact of global warming. Furthermore, this research provides a theoretical basis and a promising method for recycling other plastic-packaged e-waste devices, such as integrated circuits.

关键词： Waste LED     Hydrothermal treatment     Recycling     Plastic PPA degradation     Packaging materials    

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Special issue on “Green chemical process and intensification”

《化学科学与工程前沿（英文）》 2022年 第16卷 第11期   页码 1533-1535 doi: 10.1007/s11705-022-2263-y

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Special Issue for the Future Chemical Engineering Scholars of Global Chinese Chemical Engineering Symposium

《化学科学与工程前沿（英文）》 2022年 第16卷 第6期   页码 775-776 doi: 10.1007/s11705-022-2172-0

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Insight of chemical environmental risk and its management from the vinyl chloride accident

《环境科学与工程前沿（英文）》 2023年 第17卷 第4期 doi: 10.1007/s11783-023-1652-x

摘要： The combustion of vinyl chloride (VC) after the train derailment accident in Ohio, USA in February, 2023 has caused widespread concern around the world. This paper tried to analyze several issues concerning the accident, including the appropriateness of the VC combustion in the emergency response in this accident, the meanings of so-called “controlled combustion”, the potential environmental risks caused by VC and combustion by-products, and follow-up work. In our view, this accident had surely caused environmental and health risks to some extent. Hence, a comprehensive environmental risk assessment is necessary, and then the site with risk should be comprehensively remediated, hazardous waste should be harmlessly treated as soon as possible. Finally, this accident suggests that further efforts should be taken to bridge the gap between chemical safety management and their environmental risk management.

关键词： Vinyl chloride     Combustion     Chemical safety management     Environmental risk     Emerging contaminants    

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我国林产化学工业发展的新动向

宋湛谦

《中国工程科学》 2001年 第3卷 第2期   页码 1-6

摘要：

林产化学工业是将可再生的森林资源经过化学加工生产出各种有用的产品。它是森林资源高效可持续利用的一个重要组成部分。文章介绍我国林产化学工业的现状，并指出今后发展方向，即加强创新研究，开发深加工产品；推进林产化工企业向大型化发展；发展木材制浆造纸和开发木质能源。

关键词： 林产化学工业     森林资源     化学加工    

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Bioinspired and biomimetic membranes for water purification and chemical separation: A review

《环境科学与工程前沿（英文）》 2021年 第15卷 第6期 doi: 10.1007/s11783-021-1412-8

摘要：

•The history of biological and artificial water channels is reviewed.

关键词： Aquaporins     Artificial water channels     Biomimetic membranes     Chemical separation and water purification    

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Chemical transdifferentiation: closer to regenerative medicine

null

《医学前沿（英文）》 2016年 第10卷 第2期   页码 152-165 doi: 10.1007/s11684-016-0445-z

摘要：

Cell transdifferentiation, which directly switches one type of differentiated cells into another cell type, is more advantageous than cell reprogramming to generate pluripotent cells and differentiate them into functional cells. This process is crucial in regenerative medicine. However, the cell-converting strategies, which mainly depend on the virus-mediated expression of exogenous genes, have clinical safety concerns. Small molecules with compelling advantages are a potential alternative in manipulating cell fate conversion. In this review, we briefly retrospect the nature of cell transdifferentiation and summarize the current developments in the research of small molecules in promoting cell conversion. Particularly, we focus on the complete chemical compound-induced cell transdifferentiation, which is closer to the clinical translation in cell therapy. Despite these achievements, the mechanisms underpinning chemical transdifferentiation remain largely unknown. More importantly, identifying drugs that induce resident cell conversion in vivo to repair damaged tissue remains to be the end-goal in current regenerative medicine.

关键词： cell therapy     cell transdifferentiation     chemical compounds     small molecules     tissue regeneration    

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标题 作者 时间 类型 操作

Effects of sulfur on variations in the chemical speciation of heavy metals from fly ash glass

期刊论文

Trends of chemical speciation profiles of anthropogenic volatile organic compounds emissions in China

Wei WEI, Shuxiao WANG, Jiming HAO, Shuiyuan CHENG

期刊论文

Chemical speciation and anthropogenic sources of ambient volatile organic compounds (VOCs) during summer

LU Sihua, LIU Ying, SHAO Min, HUANG Shan

期刊论文

Sequence of the main geochemical controls on the Cu and Zn fractions in the Yangtze River estuarine sediments

Shou ZHAO,Dongxin WANG,Chenghong FENG,Ying WANG,Zhenyao SHEN

期刊论文

Effect of lime on speciation of heavy metals during composting of water hyacinth

Jiwan SINGH,Ajay S. KALAMDHAD

期刊论文

Comparison of masking agents for antimony speciation analysis using hydride generation atomic fluorescence

Jianhong XI,Mengchang HE,Kunpeng WANG,Guizhi ZHANG

期刊论文

The speciation, leachability and bioaccessibility of Cu and Zn in animal manure-derived biochar: effect

Qi Lin, Xin Xu, Lihua, Wang, Qian Chen, Jing Fang, Xiaodong Shen, Liping Lou, Guangming Tian

期刊论文

Speciation evolutions of target metals (Cd, Pb) influenced by chlorine and sulfur during sewage sludge

Jingde LUAN,Rundong LI,Zhihui ZHANG,Yanlong LI,Yun ZHAO

期刊论文

Recycling from Waste Light-Emitting Diode Under Hydrothermal Condition: Plastic Package Degradation, Speciation

Yongliang Zhang,Lu Zhan,Zhenming Xu,

期刊论文

Special issue on “Green chemical process and intensification”

期刊论文

Special Issue for the Future Chemical Engineering Scholars of Global Chinese Chemical Engineering Symposium

期刊论文

Insight of chemical environmental risk and its management from the vinyl chloride accident

期刊论文

我国林产化学工业发展的新动向

宋湛谦

期刊论文

Bioinspired and biomimetic membranes for water purification and chemical separation: A review

期刊论文

Chemical transdifferentiation: closer to regenerative medicine

null

期刊论文